Oh well theres lots of guides for this mobo, this guy gonna help you?
Anyway some guides:
Retail Leopard 10.5.6 Gigabyte GA-G31M-ESL2 - InsanelyMac Forum
Success with my (GA-G31M-ES2L - Intel Core 2 Duo E8400 3.0GHz) build - InsanelyMac Forum
You can check how to dualboot with vista in the dual boot section or just google it 
Good Luck and report back if you have any issues
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HP Pavilion Elite m9250f
iAtkos v5i (10.5.8), Asus IPIBL-LB MOD BIOS, Intel Quad Core Q6600, 4GB RAM (800mhz), 2x500GB, nVidia 8600GT (Works), ALC888S (Works), Wireless RT73 (Works), LAN (Works) - How to Install - Blog - Hardware Combos - FAQ by TJ2K7
Macbook Pro 13"
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